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Natural
rubber latex is harvested from the Hevea brasiliensis tree. The
drc in NR latex is increased to 60% or more to improve the
economics of transportation by subjecting the field latex to
centrifugation. NR latex concentrates need to be preserved with
suitable preservatives to inhibit bacterial growth which would destabilized
the latex and ultimately resulted in spontaneous coagulation.
The
types of natural rubber latex that are commonly used for the
manufacturing of examination gloves are HA (High Ammonia) or LA
(Low Ammonia) centrifuged latex concentrate.
The
raw latex concentrates are highly specified materials where the
most commonly used specification is outlined in ISO 2004 : 1979.
Concentrate
latex is delivered in road tankers.
Basic
principle of compounding is the process of mixing of latex
concentrate with various curative dispersion and chemical
stabilizers to achieved the desired processing behavior and
product properties. Latex compound for examination gloves have
four main components : Latex, stabilizer, vulcanizing agent and
protection system. Other than that, ingredients that need to be
included are pigments such as titanium dioxide, processing aids
e.g., deformers, de Webbers, mould release agent etc.
Compounding
mixing tank is specially made from stainless steel. The bottom
of the mixing tank is an inverted cone with 2 discharge valves
positioned at the apex and midway along the incline. It is
designed in this way so that compounded latex of homogeneous mix
can be discharged to lines by gravity feed. A stirrer is
provided for continuous stirring.
After
latex is compounded, the latex will be allowed to mature for a
period of time. This has to be strictly observed prior releasing
latex to the dipping tank. The purpose of maturation is to allow
initial vulcanization and also to release air bubbles entrapped
during compounding.
The
matured latex is then supplied to the production line through a
rubber hose. The release of latex into the dipping tank in each
line is automatically controlled by a electro-pneumatic level
sensor.
Laboratory
approval are obtained prior to release for use, the degree of
maturation is check by means of chloroform number or swelling
diameter test.
The
production line is a 100 meters chain conveyor type. The chain
conveyor travels through 6 loops. Lowest loop progressing
through the former cleaning and dipping processes. The upper
loops traveling through the beading station vulcanizing, drying,
post leaching and powdering.
Heat
is transferred to the whole production system through closed
loop boiler system. For a better and even temperature
distribution in the vulcanizing oven, forced circulation is
used. Ducting along the length of vulcanizing oven also assists
in the even distribution of temperature.
Porcelain
formers are attached on both sides on the chain conveyor and
with approximately of 13,000 – 15,000 pieces former per line.
The
movement of the formers is achieved by different contour steel
plates along the line. The whole chain is driven by a variable
speed controller.
Gloves
coming out from the vulcanization oven are peeled at the front
end of the line. After the gloves are peeled, the surface of the
formers will be left with process residues. Before the formers
are again dipped in the latex compound, the residues need to be
removed. This is achieved by dipping the former into Nitric Acid
solution.
The
acid left over on the formers are then rinse by running water
with sprinkle system then dip into an alkaline former cleaner to
remove the yellow stain on the former at the same time to
neutralize the reside acid on the former.
The
formers are then rinsed by dipping the formers into rinse tank
at an elevated temperature.
The
formers are then dipped into coagulant surface solution, it is
essential to avoid entrapping of air bubbles in the coagulant
solution to avoid excessive pinhole in the final product.
The
former with a layer of coagulant solution are then channeled to
a short oven to achieve a just dry stage (neither too dry nor
too wet)
The
formers are then dipped into the latex dipping tank, then
through a short oven again before 2 units of leaching tanks to
remove all soluble chemicals and non-rubber particles.
Then
the formers shall go into another curing oven before beading is
done with a set of beading brushes.
Next,
the formers will go into a long vulcanizing oven to complete
full vulcanizing drying before gloves are post leach to leach
out all soluble protein. Then formers will be dipped into a
modified cornstarch solution and go through another short oven
to complete the full vulcanizing drying before gloves are brush
and air stripped from the former.
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